| Termijn | Thuis | Uitteam | Uitslag |
|---|---|---|---|
| 3-1-23 19:00 | Espanyol Barcelona | Celta Vigo | 3:1n.v. |
| 3-1-23 19:00 | FC Cartagena | FC Villarreal | 1:5 |
| 3-1-23 19:00 | CF La Nucia | FC Valencia | 0:3 |
| 3-1-23 21:00 | Sporting Gijon | Rayo Vallecano | 2:0 |
| 3-1-23 21:00 | UD Levante | FC Getafe | 3:2 |
| 3-1-23 21:00 | AD Ceuta FC | FC Elche | 1:0 |
| 3-1-23 21:00 | CP Cacereño | Real Madrid | 0:1 |
| 4-1-23 19:00 | Linares Deportivo | FC Sevilla | 0:5 |
| 4-1-23 19:00 | CF Pontevedra | RCD Mallorca | 0:2n.v. |
| 4-1-23 19:00 | UD Logrones | Real Sociedad | 0:1 |
| 4-1-23 20:00 | Real Oviedo | Atletico Madrid | 0:2 |
| 4-1-23 21:00 | Deportivo Alaves | Real Valladolid | 1:0 |
| 4-1-23 21:00 | CF Intercity | FC Barcelona | 3:4n.v. |
| 5-1-23 16:00 | Gimnástica Segoviana CF | CA Osasuna | 1:2n.v. |
| 5-1-23 16:00 | CD Ibiza Islas Pitiusas | Real Betis Sevilla | 1:4 |
| 5-1-23 21:00 | Eldense | Athletic Bilbao | 1:6 |